Pit, the following are the system requirements for the Intel® Smart Response Technology. You will be able to see that it will work on a Single Hard Disk Drive (HDD) or multiple HDD’s in a single RAID volume only.
http://download.intel.com/support/chipsets/sb/intel_smart_response_technology_user_guide.pdf
- Intel® Z68 Express Chipset-based desktop board
- Intel® Core™ Processor in the LGA 1155 package
- System BIOS with SATA mode set to RAID
- Intel Rapid Storage Technology software 10.5 version release or later
- Single Hard Disk Drive (HDD) or multiple HDD’s in a single RAID volume
- Solid State Drive (SSD) with a minimum capacity of 18.6GB
- Operating system: Microsoft Windows* Vista 32-bit Edition and 64-bit Edition, Microsoft Windows*
- 7 32-bit Edition and 64-bit