Hi rustyspoork, I understand you would like accelerate another hard drive on your computer using separate SSD drive.
At this point, the Intel Rapid Storage technology does not allow accelerating second hard drive on same computer. I will make sure to point this out to the appropriate department for future hardware technologies.
Refer to the link below for more information:
http://www.intel.com/support/chipsets/sb/CS-032826.htm
Allan.